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Fennekin learns flamethrower at 35. And it gets psywave, luckychant and psyshock before, but I don't remember the levels.
Edit: will-o-wisp at 38
Edit2: psychic at 41
Edit3: sunny day at 43
Hello, I'm wondering if there is a way to breed a cleffa\clefariy on emerald that will get the magic guard ability when transferred to a fourth generation game?