The first set should be more like this
Leech Seed
Flamethrower/Lava Plume
Toxic/Grass Knot
Synthesis
The Fire stab should be used over hes Grass one if your going to use Toxic so you will hit Steel/Poison types harder which resis toxic.
If your going to run Toxic its better to use Flamethrower than Lava Plume.
Also Pyroak really needs Synthesis as it would be useless without it as every time he switches he loses 25% and it helps him alot with healing/stalling.
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