Another duo I've seen a bunch of people do is Mamo+Amoo under hail. They work together well, but they require a water type (kingdra lol) to take fire for them. Here's how they synergize:
covered by Mamo:
-wall-breaking dragons
-flying types that love to drop bombs below (lol)
-other grass walls
-steel types
covered by Amoonguss:
-twave to help with mamo's slow speed
-bulky water walls
-fighting types (well, not really, but it can wall them all day)
-can but threats to sleep
Their synergy isn't perfect, but it's very good.
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