Froakie
Ability: Protean
Level: 5
EVs: 28 HP / 228 Atk / 36 Def / 4 SpD / 188 Spe
Jolly Nature
- Taunt
- Thief / Waterfall
- Acrobatics
- U-Turn
I've actually almost used this once which makes me an authority on it. Essentially, itemless Froakie is and always will be the way to go to abuse Thief and Acrobatics. The point of this set is Taunt as with it, Froakie has a chance to block hazards and support your team. A potential first turn would be, say, Taunting a Dwebble and using Thief or U-turn on a switch. I don't include Waterfall since it's not necessary and since Acrobatics is your main STAB move; be careful not to steal an Eviolite when using Thief. Because that risk exists, you can use Waterfall instead of it, but it's nice grabbing Berry Juice and shit.
I like Taunt Froakie.