It's all probability. You can catch a full-strength Mewtwo with a single pokeball if you get lucky; you can miss with 100 duskballs in a row if get really unlucky. Picking the outlier cases from 50-100+ hours of gameplay is going to give you weird results almost by definition.
Regarding an untouched Azelf in a single quick ball, the gap between 4x and 5x isn't really that much of a windfall anyway: it's 1.6% at 4x and 2.0% at 5x.
As for the Gligar, I'm not sure how weakened is weakened, but at max HP the odds are 80/256 and at min 240/256. If you had it at totally minimum HP and/or inflicted with status then something may be amiss, but anything above 1/4 HP and you have an unlikely but very possible (if frustrating) situation.
Really the only time you can say anything conclusive is when you either set up a situation in which a certain outcome MUST occur (ie, the first time a Quick Ball fails to catch a 190-200 you know it must be <4x, because it should have a 100% catch rate at 4x) or you do a whole bunch of attempts to thin out short-term probabilitistic screwing/blessing. And all of this is making the assumption that those formulas are correct.
Regarding an untouched Azelf in a single quick ball, the gap between 4x and 5x isn't really that much of a windfall anyway: it's 1.6% at 4x and 2.0% at 5x.
As for the Gligar, I'm not sure how weakened is weakened, but at max HP the odds are 80/256 and at min 240/256. If you had it at totally minimum HP and/or inflicted with status then something may be amiss, but anything above 1/4 HP and you have an unlikely but very possible (if frustrating) situation.
Really the only time you can say anything conclusive is when you either set up a situation in which a certain outcome MUST occur (ie, the first time a Quick Ball fails to catch a 190-200 you know it must be <4x, because it should have a 100% catch rate at 4x) or you do a whole bunch of attempts to thin out short-term probabilitistic screwing/blessing. And all of this is making the assumption that those formulas are correct.