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Maybe, although exclamation marks are fewer in numbers than overworld Pokemon, which are Brilliant at random and so, could be harder to come across, especially if one doesn't care about them at all. Official info about this only talks about the Wild Area and how to raise Brilliant Pokemon's...

They're aura Pokemon.

Could some dataminer chime in on whether random encounters can be Brilliant Pokemon or not? A reddit poster claimed to have seen a glowing yellow ! mark before an encounter but apparently, no one else talks about this. If overworld, raids and fishing can spawn Brilliant Pokemon, it would be...