Welcome to Smogon! Take a moment to read the Introduction to Smogon for a run-down on everything Smogon, and make sure you take some time to read the global rules.
During the week, I'm available from 8:00 PM until midnight (UTC-3), except on Tuesdays which are pretty bad for me the whole day. During the weekend, I expect to be online at pretty much anytime.
We can try playing tonight if that's ok with you.