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Illumise

I've tried her before. She's okay...except for the fact that Sableye & Murkrow ENTIRELY out-class her.

Illumise (F) @ Leftovers
Trait: Prankster
EVs: 132 HP / 248 Def / 128 SDef
Impish Nature (+Def, -SAtk)
- Charm
- Encore
- Toxic
- Moonlight

It's like Sableye...except it's never leaving NU. In fact, it's bulkier than Sableye...slightly. Oh and it lacks Taunt. All it really does is annoy Physical Sweeper to no end.

She also has Covet to steal an item if you don't like Toxic...she has like 6 good moves.
 
I think instead of focusing on recovery, you could use that set to force switches. With priority subpass and a simple resist to fighting-type attacks, it could potentially work on a stall-ish team by forcing switches and giving stat reductions:

Illumise @ Leftovers
252 HP/252 Def/4 SpDef
Bold / Prankster

Charm
Encore / Struggle Bug
Substitute
Baton Pass

Charm a physical sweeper, throw up a Substitute, baton pass out to a counter to the inevitable special attacker that comes in. Think Murkrow but with actually good physical resistances and the ability to bp out of a bad matchup as a tradeoff for lack of reliable recovery. Covers Blissey/Chansey's only type weakness and is fully recovered by Wish. Can also threaten to lock sweepers into stat-up moves that continue boosting to avoid Charm with Encore, such as swords dancers that will continue to boost. Yeah, Illumise isn't going to do much damage no matter what moves it has, but Struggle Bug is also a potential option to soften the switch-in to your special wall and guard against mixed attackers, since the spatk drop is guaranteed and isn't affected by gender (and you can still bp out if you mispredict). Hazards greatly limit this set, but you wouldn't run this shit on anything but a stall team, so ideally you'd keep hazards off so Ilumise can come in to be healed by Wish. Just to show you that this isn't ridiculously fragile once it gets in, here are a few example calcs that assume you stay in and charm the opponent (standard natures):

Vs. CB Haxorus Outrage: (54.79% - 64.67%)
Vs. CB Terrakion Stone Edge: (76.05% - 89.82%)
Vs. LO Sand Force Landorus Stone Edge: (55.09% - 65.27%)
Vs. +1 Guts Conkeldurr Payback: (38.92% - 46.11%)

The calcs aren't really that relevant because you'll just be overwhelmed most of the time by the power of opponents' moves, but a set like this has good viability in lower tiers, where it can actually stay in and take more than two hits without dying, and potentially running Moonlight over Encore to support itself with recovery while softening up threats for the rest of your team to stall. The ability to get something like a Wish+CM Jirachi in on a -2 Hax Outrage with a sub intact can be game-changing, which with the old school physically bulky Wish+CM Spread can actually result in illumise's BP'ed substitute being unbroken by adamant hax's cb outrage. Examples like that are situational and need to be tailored, but the idea is solid by itself.
 
In fact, looking at that set, it should probably be something more like this...

Wallumise?
Ability: Prankster (Duh)
Nature: Calm
EVs: 252 HP, 252 Sp. Def, 4 Def/Sp. Attack (It really doesn't matter)
Item: Leftovers
Moves:
-Bug Buzz/HP Fire
-Toxic/Thunder Wave/Substitute/Protect
-Moonlight/Wish
-Charm

This way you don't have to limit yourself by using two moveslots for Charm and Captivate. Run Max Sp. Def and use Charm for physical attackers. Bug Buzz is standard Bug-Type special stab, but HP Fire can be used to hit steels you can't Toxic. Toxic/T-Wave is for support, though I recommend Toxic to slowly pick off your enemies. Substitute or Protecct could be used, especially if you are running Wish. Moonlight is for (almost) reliable recovery, but Wish could be used ONLY if you are running Protect or Substitute. This set I think will actually work like well, for right now SABLEYE is really doing well being bulky thanks to priority recover and Will-O-Wisp, and Illumise has better defensive stats. I think this is quite runnable in RU, and maybe in UU, (though with so many powerful Fire types there now I'm not sure!)
 
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