In my opinion, the pokemon that has gained the most from the generational shift is probobly Celebi.
Firstly, I hardly count Gen 4 Rotom-W as the same pokemon as Gen 5 Rotom-W. They have different types. Even then, Gen 4 Rotom-W was hardly bad, just the Dragon dominated metagame filled it with steels, which got cooked by the oven. And there wasn't rain on 15+% of teams either [Hence ~30% of games]. Volt Switch is something all Rotom Formes benifit from.
Celebi:
Gained Nasty Plot
Gained Psyshock
Gained a metagame with fewer Fire types and Fire-type attacks being used
Benifits greatly from the increased prominance of Water-types.
Meanwhile, all of it's old sets ARE STILL VIABLE.
About the only real downside to Celebi is it has to choose between Scizor killing it/Ferrothorn walling it, or Dragons having a feilday. But that was the case in Gen 4, and Celebi can still fire off a T-Wave/Toxic easily at them, and you DO have 5 other team members.