Hey Espeon, it seems you are new here, and I am no pro to NU, but some suggestions. Like you have said, Volcarona is in BL, basically OU, but Mega Scizor is also OU, so I wouldn't bring it up here. Secondly, since Muk is more of a bulky Pokemon than a cleaner, Poison Jab is basically always preferred, as it along with Poison Touch gives a 60% chance to poison the opponent, as well as being reliable with 100% accuracy. Regarding your second moveslot, Mega Steelix is huge in this tier, and Fire Punch is doing nothing to it, and Rock Slide doesn't provide much, only giving you a super effective hit against Archeops, while other bug, flying, and fire types are hit hard by Poison Jab. I would suggest Earthquake, as it hits M-Camerupt for super effective damage, as well as bulky rock types and opposing Poison types immune to your poisoning. Priority is fine to secure double downs after poison damage, and finishing off a Typhlosion in Blaze. Fourth moveslot is best to be Ice Punch or if Mega Steelix is a super big threat to your team, you could try Focus Punch, hitting it hard on the switch, weakening it for another Pokemon to finish off. While Ice Punch hits ground types that threaten Muk with their STAB super effective EQs and such.
btw, Welcome to Smogon! :)